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FAQs on Calcium, Supplements involving Calcium, Testing/Measuring
Related Articles: Calcium, The Use of Kalkwasser by Russell Schultz, Understanding
Calcium & Alkalinity, Live Sand,
Marine Substrates, Reef
Systems,
Refugiums, Related FAQs:
Calcium, FAQs 1, Calcium, FAQs 2, Calcium
FAQs 3, Calcium FAQs 4,
Calcium FAQs 5, Calcium FAQs 6,
Calcium FAQs 7, & FAQs on Calcium:
Rationale/Use, Sources of Calcium,
Calcium Supplements, Dosing,
Chemical/Physical Interactions,
Troubleshooting/Fixing, &
Calcium and Alkalinity, Calcium
Reactors, & FAQs
on Calcium Reactors:
Rationale/Use, Selection,
Installation, Operation,
Media, Measuring,
Trouble-Shooting, By Makes/Models,
& Kalkwasser, &
FAQs on: The Science of Calcium & Alkalinity,
Importance, Measure,
Sources, Use of Additives, Troubleshooting/Fixing,
Products, |
Get/use "good" test kits... Hach, LaMotte, Aquarium Systems,
Salifert... but whoever's you acquire, do keep up on the "freshness"
dates of their reagents. Rinse all gear before and after with
clean water... thoroughly mix reagents and test samples... Compare
colorimetric assays against white paper backgrounds in good light. |
Salifert calcium test 4/16/07 Hello crew, I am
wondering if anybody out there knows how to get in touch with Salifert
regarding their test kits. <Mmm... well, their website:
http://salifert.com/ doesn't list contact information... and they're
made in Holland...> I had heard nothing but good things about their
products so purchased a Salifert Ca Profi test kit from the LFS to
compare a suspect API calcium test kit I have. I had low calcium on a
new tank set up with live rock that has just been cured (API -360-380)
and purchased some Seachem calcium supplements to get the Ca up. The API
kit showed the CA rising to normal levels 400-460 and stabilizing at
about 440. Knowing the API kits are middle of the road I wanted a
benchmark to know if these results are accurate, so I purchased the
Salifert kit. The first day the new kit told me my Ca was about 370
mg/l same as the API at the time. The second day API 400 after dosing
supplements Salifert 370 mg/l. third day API 420, Salifert 370.
yesterday and today 440mg/l -API , 375mg/l- Salifert. Now here is where
it gets interesting, Salifert- good API -ok or so one would think.
My wife who works at a local hospital as a laboratory scientist, ran a
sample of my water through a very expensive chemistry analyzer (Sundays
are slow) showed calcium at.... drum roll please.... 441mg/l, dead on
with the API kit. I even had her perform the Salifert test this
morning (this is what she does for a living as a lab scientist) with
the same results She also pointed out to me that temperature and high
humidity such as found in your LFS full of aquarium tanks could affect
the reagents in a negative way and any reagents in her lab are stored
with desiccants. I would like to contact Salifert to advise them of
what I found, maybe a bad test reagent(s) <Am sure they will/would
appreciate this... I would write to them via their master
distributors... Quality Marine in the United States, or Tropical Marine
Centre in the U.K., depending on where you are... Both companies have
websites, contact info. posted...> I am a bit disappointed because
I've heard such great things about them and would use the test as a
benchmark for the cheaper (API) test. Any info you kind folks could give
would be greatly appreciated. I tried their website but it has no
contact info and the box only has a European phone number. thanks guys
and gals, John P <Ahh, yes... I too have heard little negative re
this companies main stream assay/kits... But as your wife states, there
are many influences to the reagents... Bob Fenner>
Calcium
test kit accuracy 10/03/04 I have read several of the FAQ's on
calcium, and still have a question. I have a 125g that I started Sept.
1. I added 125lbs of un-cured LR on Sept. 11. Euro-reef skimmer (in
sump), fluidized bed. A lot of my LR has a white coating on it - like a
crust. <assuming you have adequate water flow for curing
rock (20X+ turnover of the tank?), this may simply be decay from hard
curing rock> My calcium readings are off the chart (>500ppm).
<this seems very highly unlikely after even a few hours (without
precipitating). Much more likely that you are getting a misreading from
your test kit. Even new kits can give false readings. Do take a water
sample to a friend or the LFS for a test of CA on a different type or
brand of test kit> I read about the possibility of a "snow storm"
and it is scaring the crap out of me. <no worries...
you would have to be/have been adding obscene amounts of Ca> I
changed 19gallons of water today, using DI water - <yikes! now that
is dangerous. Never, ever use/add raw DI or RO water. Always aerate for
12+ hours then buffer 2+ hours in advance of salting or using for evap
water> calcium is still off the chart. <I see... all
the more reason after using demineralized water to believe that this is
a misreading on your test kit> I have only added Bi-onics only once.
Today I just added the Alkalinity part (part 1) in the hopes of driving
the calcium down. What to do? <I'm as certain as I can be from
here that you have a bogus test reading... test again my friend.
Anthony> Test Kit I would like to know
your opinion on Seachem's calcium test kit , I can get it at a good
price at LFS. I know you guys normally recommend Salifert brands but it
is a lot more expensive. Should I pay the extra money for Salifert or
will the Seachem's kit be fine? Thanx for help. <It's really a matter
of preference. I have used both with good results. I find Salifert's kit
to be a bit more consistent, but it can be a bit trickier to use than
Seachem's. Both are excellent companies that make some very fine
products. I don't think that you'd do too badly with either one. Good
luck! Regards, Scott F> Does His Water Has More Calcium Than A
Quart of Milk? Hello All, <Hi there. Scott F. here!> I'm
here again with another learning project. <All part of the fun!>
I'm wondering if you could help direct me in interpreting my SeaTest
Calcium test kit results. I just bought this kit today and promptly
tested my water, carefully following the directions. According to the
test (I ran it twice to be sure) I'm running at 1080 mg/1 Ca. <Gosh-
I certainly hope not...! LOL> The test kit itself says it only tests
0 to 500 mg. So if your familiar with this kit, when you get to reagent
3 you add drops and swirl on each drop until the test water turns pure
blue. <Right..> My test water started to change at drop 62 and
became pure blue at drop 72, you now multiply 72 *15 =1080.
<Hmm...something is definitely amiss here! A dumb question, but are you
sure that you rinsed the measuring tube in tank water before commencing
the test? Did you fill Reagent #1 to the mark shown on the dropper in
the kit? Another possibility-Did you get all of the contents of the
granular reagent out when you performed step 3? Just some thoughts.>
If I understand all this, I'm very high on my Ca. Is this a bad thing?
<Well, excessively high calcium could be a big problem, but you'd
probably notice a "snowstorm" in the tank, as there is only so much
calcium that can stay in solution. Unless you have been adding a ton of
calcium supplements in a (no nice way to put it) reckless manner, or
your source water contains extremely high amounts of calcium to begin
with, I'd say that the problem lies with the testing procedure, expired
reagents, etc. Maybe you should take a sample to a dependable LFS for a
calcium test to see if they get the same result. At least this will
eliminate the possibility of ultra-high calcium levels if the test
results in a "normal" reading. Also, you may want to contact Aquarium
Systems regarding the problem you are having. They may offer a
recommendation for correction, or some other remedy for this problem>
Tank is a 55g started November 16th 2002. Removed crushed coral
substrate 1 week & 2 days ago and replaced with 4" DSB. (My wife
suggested out that the new sand bed is probably the cause of the high Ca
here). Could she be right AGAIN? :-) <Well- "high" is a relative
term. There is "high" (like 400-450 mg/l), and then there is HIGH (1080
mg/l)! Deep sand beds certainly help maintain high calcium levels, among
other benefits-but the level that you are recording is really
unusual...Try the suggestions that I made...hopefully, you'll get things
straightened out!> Thanks in advance for the help. Dave <Thanks
for stopping by, Dave- and Good Luck! Regards, Scott F> Calcium
Tests-Shaken Not Stirred??? Kind Sirs, < No "sir" needed!
Scott F. here today!> I have a question regarding the Calcium test
kit by Aquarium Systems. Guess to be quite honest do I blame the test
kit or the tester??? <It's a good hobbyist test kit, IMO. Certainly
not as accurate as a LaMotte or a Salifert, but I like it myself> I
thought I read that on the site, that although it's not one of the best,
it is an inexpensive test kit to help monitor calcium levels. <Yep>
It happened to be carried by my LFS. But testing for the past week
(first time calcium tester) I haven't been able to get a reading below
the 500 limit. The test never changes over to its "true blue" color. If
I may go through the >process. Step 1 small vile of tank water, seems
easy enough, taken from the top of the tank to prevent hands from
entering the tank. Reagent 1 to line indicated, again thought I could
handle it, do shake reagent before filling dropper to mark line. Reagent
2, dated March 04, figure still good. Swirl to mix. Should this be
stirred??? <Nope- just swirled> Then adding drops of reagent 3.
Directions indicate swirl after each drop? <I'd swirl after each
drop> Usually swirl after adding 5,problem??? <This might be>
Also should this be stirred??? <nope- I wouldn't stir> A brief
supplementation history: Tank 30 gal, about 20 lbs of live rock, upon
recommendations of LPS, when purchasing last few lbs of rock, Bought and
used Kent calcium, Kent Strontium and Kent Essential Elements. Up until
that point I never supplemented anything to the tank. (4 years). Found
your site, learned about the ion problem of calcium chloride, strontium
supplementation is not really required but still use the Essential
Elements to add iodide to the tank (for cleaner shrimp), <I think
that you'd do better to just make frequent (2x weekly) small water
changes. If you are going to use additives, you need to test for them>
Added calcium, a capful every 4 days up until 2 weeks ago (for about 1
month total), I was going to finish the bottle, figured with water
changes and only using calcium chloride about 3 to 4 months I
wouldn't have an ion problem. (But I learned that I should test before
supplementing so I stopped adding until I can get the test kit figured
out.) <Great move on your part- you will not regret doing it this
way> PH always test around 8.4, no variation between day and night,
figure it's the new (closed) house situation that I read about. And alk
is always around 3.4 meq. I think it's on the low side, <Actually,
that's a good reading, IMO> only buffer added is Red Sea Buffer that
came with the test kit, added to Water change water (not to tank) after
instant ocean salt added and aerated overnight. <Good technique,
aerating the water before use, particularly if you're using R/O> Not
sure if any other tank condition would affect the test. Water changes
are 4 gal every two weeks. Also, does SeaChem Calcium have a shelf life?
<Yes it does- I'd consult them for specifics (see the link to them on
our site> LPS has a few small bottles, (it mostly carries Kent
products), and from the dust covering looks like it's been there awhile.
Figured I'd switch to SeaChem after using up the Kent Calcium. The only
calcium requirements I have for my tank at the moment is for Coralline
algae growth. <Seachem calcium is Calcium gluconate, and this stuff
will grow coralline like crazy, if used correctly. I'd use Seachem's
test kit if using this product, by the way> Coralline consists
of some purple and green growth (little) some bleaching but leaned
that's from improper dosing. Think it's form lack of, not excessive.
<Lots of reasons for coralline declines> The only other calcium test
kit available from LPS would be Red Sea. Would it be worth purchasing
and testing or should I look to purchase test kits online? I'd stick
with the Sea Test for now, and switch to the Seachem if using their
calcium product. (would like to avoid if possible-tank spending
monitored to easily) Temp is a steady 78 degrees and salinity is
1.021. <Sounds fine> Thanks for your help, DaveK <Well, Dave-
sounds like you're on the right track...Just keep thinking about making
your hobby as simple as possible. Unless you have very specific reasons,
I'd avoid using lots of different additives. Remember, the adage that we
both touched on "don't add something to the water unless you are going
to test for it". In many cases (there are, of course, exceptions),
simply executing regular water changes can provide all of the trace
element replenishment that you will need to maintain a healthy system.
If you keep things simple, you'll enjoy your hobby so much more, and
will really be successful in the long run! Good luck! Regards, Scott F>
Calcium Level Hi Bob, <Anthony Calfo in your service> I'm
having a problem along with everyone else on maintaining my calcium
level. Currently it's been 700+. <this is almost certainly a
misreading my friend... if not an outright impossibility. Crystalline
precipitation of calcium carbonate begins easily in most tanks by
500ppm. Anything over that is very difficult to even achieve. Do test
this water with an entirely different brand of test kit. Try Aquarium
systems ReefTest kits> I read your FAQ's and found that if you add
backing soda to your Reef Tank, it will lower your calcium. However, it
will raise you pH level. <fast and temporarily... easily abused too>
I have lost a lot of live rock and other creatures and I'm getting
frustrated. Would you please give me some help on keeping my Reef Tank
in proper condition such as the levels and what type of chemicals to use
in maintaining my Reef Tank? God Bless, Peggy <no worries, my friend.
I suspect your primary problem is the test kit, not the water. You could
only get such readings by a repetitive and obscene overdose of calcium
supplements. I discuss water chemistry for ref aquaria extensively in my
book (http://www.wetwebmedia.com/bkcorlproprev.htm). If you are really
ambitious, do pursue the works or Dr Craig Bingman... very learned and
informative in his studies on water chemistry. Anthony Calfo>
How to measure Ca Hi, I hope everything is doing well with all of
you! <and you as well, my friend> I was reading the procedure
recommended by Anthony in his book, and its sound easy, but I have a
problem, I can't find reliable test for Ca. <indeed... the liquid
titrations are tedious and not clear. To some extent they are variable
due to the differences in each of our eyes to perceive colors. But some
kits are just plain inconclusive. For an inexpensive and reliable kit, I
like Aquarium Systems brand> The first day I measure it with a Red
Sea (liquid) reagent and it shows 300 ppm (scale from 50 to 50) that
nigh I dosed one glass of super ultra archi full loaded and
hypersaturated solution of Kalk (wink as Anthony says) the very next day
I use the meter again and it show only 300, so that night I dosed again
another glass (concentration 1/8 tea spoon) the next morning the same...
300, so I repeated everything but the same reading 300... The Ca is
going up, I'm sure, because the red algae is growing at a seeing rate,
my 3 shrimps are changing its skeleton, and my only Halimeda bush
increase at least one leaf at day... <excellent... and agreed. The
Ca is certainly going up. I have heard many complaints about the Red Sea
test kit specifically.> I know you can said that my tank consume 50
ppm by day, but I'm not sure at all, you will see my tank is not full (I
presume) of Ca demanded inhabitants <yes... 50 ppm is really a lot!
It is unlikely that the demand is that high although possible> 200
lts (50 gallons) 35 pound live rock (almost with nothing over the
rock) 2 small (1 inch) cinnamon shrimp (cleaning family) 1 medium
(2 inches) boxing shrimp 4 turban snails (their are growing since I'm
using Kalk) 2 damsel fish 1 yellow tang 1 little colony of
small polyps a spot of Halimeda and... nothing more <yes...
agreed... not 50ppm daily demand. The test kit is certainly inaccurate
here> PH 8.3 (average) Ammonia 0 Nitrites 0 Nitrates 0
Temp 82° I don't want to dose more Kalk until I have a correct way to
measure the Ca. I don't want snow storms... <very wise> Here I
only found Red sea Reagents and they are liquid not dry as Anthony's
book recommend, <hmmm... that's OK. I can live with a liquid reagent
if it is fresh and rotated often (do not keep longer than 6 months)>
exist an digital device like PH meter from Hanna or something more
accurate to read Ca? <too expensive> there is another way to know
how much Ca my system is using? <yes... even with a less accurate
test kit it is easier to test the daily demand by starving the tank of
calcium for several days: test the Ca before you start, then test it
several days later and divide the difference in drop by the number of
days you went without dosing Ca. This gives you a more reliable reading>
there are indirect methods to know if the Ca is too high (like high
PH?) how many angels can I seat in one square feet? <heehee...
unfortunately the indirect methods are not always reliable. Let me know
what other test kit brands are available if you cannot find Aquarium
Systems (the maker of Instant Ocean Sea Salt). Also, some of the big
mail order companies here in the US frequently sell overseas like Marine
Depot. Perhaps you could inquire about a special order if necessary>
Thanks for your prompt answer, Carlos <with kind regards, Anthony>
Re: Calcium Question I am using SeaTest and Salifert test kits
for calcium. I also took some water to the LFS today and they said my
levels of calcium were at 270ppm. You said I might be dosing too fast? I
am dosing about 1 1/2 liters of freshwater with 1/2 teaspoon of Kalk at
about 1 drop per second at night. I am dosing it into my sump right next
to the inlet <fair enough... sounds slow enough for dosing. We've
exhausted the likely causes. Do test your magnesium levels to see if
they are skewed with Ca/Alk. Magnesium should ideally be about triple Ca
(1000-1200 ideally). Best regards> Calcium and Test Kits
Crew, <<Greets...>> I just wanted to add my observations to the
discussion on today's question and answer page about calcium
concentration and suspect test kits. I thought I had the same problem
earlier this year. I was beginning to add calcium to an 8 year old tank
(FO) to which none had been added before and was monitoring calcium and
alkalinity. Calcium levels were not rising (alkalinity was improving)
and I suspected either 1 the test kit, or 2 my forest of cancerous
Halimeda. Through persistence and continued monitoring I have finally
gotten the level up into the mid 300ppm (Salifert kit) and my alkalinity
is maintained around 10dKh. It has taken months and nearly a gallon each
of ESV's two-part product! <<Time for a calcium reactor...>> My
explanation is that the tank has been deficient for so long that the
substrate and live rock have absorbed it back to reach "equilibrium"
levels. Am lost as to what else it could be - the fish? <<Not the fish
either, just not really possible to pour in calcium and get a perfect
reading in one day, and quite likely the forest of Halimeda was sucking
it back out just as quickly as you put in the calcium. Sometimes very
hard to get ahead of demand.>> I have also noticed that at least for
my system, the alkalinity moves much faster than the calcium when using
this product. Given that the two measures are inter-related, calcium has
a lot more 'momentum' in the reaction equation than alkalinity.
Thanks for the great work you folks do! <<Glad you find it helpful.>>
David <<Cheers, J -- >> Calcium Hi Bob, I have a
question for you re: calcium, if you have the time. We have a calcium
test kit from a company called "Hagen" the test name is Ca Test. When we
perform the test, the readings are off the chart, over 800 ppm. We add
no calcium to the water, however, we live in Montana and our water
source is the Missouri River. Much of the river runs through limestone
canyons. In your opinion, do you think that it's more likely the test is
inaccurate, or would you think that our calcium could be that high?
<This is very high... but possible... Yikes, "liquid rock", even rockier
than good ole San Diego...> The reason I question this is because our
purple coralline algae looks like it's bleaching out. <Actually not
surprising... think about this. The corallines require both high
alkalinity and biominerals (like Ca)... but too much alkaline earth
(e.g. calcium) will greatly reduce alkaline reserve... Ah...> To
refresh your memory, we have a 125 gallon tank. Our lighting is 3, 175
watt MH and 2, 160 watt actinic. We run a Berlin style filter with a
Turbo Flotor foam fractionator and a wave maker. I think my lighting,
filtering, skimming and water movement is good. Do you think we could
actually need to add calcium? <No> Throw away the test kit? If
you think that this test kit is inaccurate, could you recommend one that
would be reliable? <Maybe have a shop "test your tester"... but it
may be fine> All of our other readings are good, with the exception
of our PH. Our PH has always, for the 5 years I've lived in Montana,
been a little on the low side. Never as low as 7.5, but never a good
strong 8.0, probably somewhere in the vicinity of 7.8 if I had to guess.
Even with water changes we can't make that figure budge. Is there a
relationship between the two? I read your web site religiously and your
column in the fish mag, but get a little confused. BTW, I'm a San Diego
native, transplanted to Montana due to job relocation. Thanks for any
input you care to share. Betsy >> <A few possible relationships at
play here... If it were me/my system and home, I'd just get and use a
decent reverse osmosis filter system for making water for aquarium use
as well as cooking and drinking... Do look into one of these (Home
Depot, Lowe's... or pet-fish relabeled brand... And don't think about
not-so sunny Cal... the traffic is horrendous here (even for dodgers
like myself who rarely venture out), and folks are becoming way to mean,
small-minded for my blood. Bob Fenner> Calcium Problem A
strange one, Bob. Began using the Salifert Calcium test a few weeks ago.
My level jumped in the last two weeks. Here are the overall readings:
Ammonia - 0 Nitrites - 0 Nitrates - 0 Ph - 8.2 Salinity -
also jumped to 1.032 <What?> Calcium - went from 450 to 1000
<Nah. Something awry here> Have begun slowly bringing the salinity
down with partial water changes, over the last four days, presently down
to 1.028. However, the calcium still is around 1000 mg/l. We ceased
adding anything that contains calcium two weeks ago, and have been using
only Coral Vital and Kent's Invert twice a week. I have been unable to
find the cause of the additional calcium. I now have the following live
stock: <Stop right here... and stop using the sugar/vital product(s)>
yellow tang royal Gramma six-line wrasse green Chromis
yellow-fin damsel yellow-tail damsel percula clown
long-tentacle Anenome peppermint shrimp emerald crabs Hermits
snails pagoda cup frogspawn mushrooms bubble finger
All appear fine except the bubble and finger, though both are coming
back around with the partial changes, 2 gallons of fresh/day, no
saltwater mix added. I intend on going to a 10 gallon change tonight,
and bring the salinity back down to 1.025, but still am concerned about
the calcium. Any ideas?? Rick Farris <There is a false positive
with the Salifert Test... you will soon be about right... just drop the
Weiss... Bob Fenner>
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